Publications

Publications (at Dartmouth)
See my Google Scholar profile here for these publications with links to their citations.

Click on the link, or the graphic, to see the abstract, or on the other link to see the paper online.
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83. Glueck, D. S. Asymmetric Synthesis of P-Stereogenic Secondary Phosphine Oxides (SPOs). Synthesis 2022, 54, 271-280.

82. Tipker, R. M.; Muldoon, J. A.; Pham, D. H.; Varga, B. R.; Hughes, R. P.; Glueck, D. S.; Balaich, G. J.; Rheingold, A. L. Configurational Lability at Tetrahedral Phosphorus: syn/anti-Isomerization of a P-Stereogenic Phosphiranium Cation by Intramolecular Epimerization at Phosphorus. Angew. Chem. Int. Ed. 2022, 61, e202110753.

81. Glueck, D. S. Intramolecular Attack on Coordinated Nitriles: Metallacycle Intermediates in Catalytic Hydration and Beyond. Dalton Trans. 2021, 50, 15953-15960.

80. Glueck, D. S. Catalytic Asymmetric Synthesis of P-Stereogenic Phosphines: Beyond Precious Metals. Synlett 2021, 32, 875-884.

79. Scheetz, P. M.; Chachula, S. T.; Hughes, R. P.; Glueck, D. S.; Moore, C. E.; Gembicky, M.; Rheingold, A. L. Synthesis, Structure, Dynamics, and Enantioface-Selective η³-Benzyl Coordination in the Chiral Rhodium Complexes Rh(diphos*)(η³-CH₂Ph). Organometallics 2020, 39, 3802-3816.

78. Zimmerman, A. N.; Xu, R. S.; Reynolds, S. C.; Shipp, C. A.; Marshall, D. J.; Wang, G.; Blank, N. F.; Gibbons, S. K.; Hughes, R. P.; Glueck, D. S.; Balaich, G. J.; Rheingold, A. L. Diastereoselective Synthesis of P-Stereogenic Secondary Phosphine Oxides (SPOs) Bearing a Chiral Substituent by Ring Opening of (+)-Limonene Oxide with Primary Phosphido Nucleophiles. J. Org. Chem. 2020, 85, 14516-14526.

77. Glueck, D. S. Metal-Catalyzed P-C Bond Formation via P-H Oxidative Addition: Fundamentals and Recent Advances. J. Org. Chem. 2020, 85, 14276-14285.

76. Gibbons, S. K.; Valleau, C. R. D.; Peltier, J. L.; Cain, M. F.; Hughes, R. P.; Glueck, D. S.; Golen, J. A.; Rheingold, A. L. Diastereoselective Coordination of P-Stereogenic Secondary Phosphines in Copper(I) Chiral Bis(phosphine) Complexes: Structure, Dynamics, and Generation of Phosphido Complexes. Inorg. Chem. 2019, 58, 8854-8865.

75. Scheetz, P. M.; Blank, N. F.; Gibbons, S. K.; Glueck, D. S.; Rheingold, A. L. Oxidative Addition of Methylene Chloride to Me-DuPhos Complexes of Palladium and Rhodium. Inorg. Chim. Acta 2018, 483, 111-115.

74. Gibbons, S. K.; Xu, Z.; Hughes, R. P.; Glueck, D. S.; Rheingold, A. L. Chiral Bis(Phospholane) PCP Pincer Complexes: Synthesis, Structure, and Nickel-Catalyzed Asymmetric Phosphine Alkylation. Organometallics 2018, 37, 2159-2166.

73. Wang, G.; Gibbons, S. K.; Glueck, D. S.; Sibbald, C.; Fleming, J. T.; Higham, L. J.; Rheingold, A. L. Copper-Phosphido Intermediates in Cu(IPr)-Catalyzed Synthesis of 1-Phosphapyracenes via Tandem Alkylation/Arylation of Primary Phosphines. Organometallics 2018, 37, 1760-1772.

72. Deegan, M. M.; Muldoon, J. A.; Hughes, R. P.; Glueck, D. S.; Rheingold, A. L. Organometallics 2018, 37, 1473-1482. Synthesis and Structure of Metal Complexes of P-Stereogenic Chiral Phosphiranes: An EDA-NOCV Analysis of the Donor-Acceptor Properties of Phosphirane Ligands.

71. Muldoon, J. A.; Varga, B. R.; Deegan, M. M.; Chapp, T. W.; Eördögh, Á. M.; Hughes, R. P.; Glueck, D. S.; Moore, C. E.; Rheingold, A. L. Angew. Chem. Int. Ed. 2018, 57, 5047-5051. Inversion of Configuration at the Phosphorus Nucleophile in Diastereoselective and Enantioselective Synthesis of P-Stereogenic syn-Phosphiranes from Chiral Epoxides.

70. Gibbons, S. K.; Hughes, R. P.; Glueck, D. S.; Royappa, A. T.; Rheingold, A. L.; Arthur, R. B.; Nicholas, A. D.; Patterson, H. H. Inorg. Chem. 2017, 56, 12809-12820. Synthesis, Structure, and Luminescence of Copper(I) Halide Complexes of Chiral Bis(phosphines).

abstract

gibbons_TOC

online

69. Scheetz, P. M.; Glueck, D. S.; Rheingold, A. L. Organometallics 2017, 36, 3387-3397. Rhodium-Catalyzed Isomerization of a Bis(secondary phosphine) to an Unsymmetrical Diphosphine via P-C Cleavage and P-P and C-H Bond Formation.

abstract

Rh_PP

online

68. Anderson, B. J.; Reynolds, S. C.; Guino-o, M. A.; Xu, Z.; Glueck, D. S. ACS Catal. 2016, 6, 8106-8114. Effect of Linker Length on Selectivity and Cooperative Reactivity in Platinum-Catalyzed Asymmetric Alkylation of Bis(phenylphosphino)alkanes.

online

67. Xu, Z.; Cain, M. F.; Rupert, A. V.; Glueck, D. S.; Golen, J. A.; Rheingold, A. L. Tetrahedron: Asymmetry 2015, 26, 1459-1468. Selective formation of a C3-symmetric P-stereogenic tris(phosphine) via platinum-catalyzed asymmetric alkylation of a tris(secondary phosphine).

online

66. Wang, G.; Guino-o, M.; Glueck, D. S.; Golen, J. A.; Daley, C. J. A.; Rheingold, A. L. Dalton Trans. 2015, 44, 9943-9954. Synthesis of a Phosphapyracene via Metal-Mediated Cyclization: Structural and Reactivity Effects of Acenaphthene Precursors.

online

65. Emerson, E. W.; Cain, M. F.; Sanderson, M. D.; Knarr, C. B.; Glueck, D. S.; Ahern, J. C.; Patterson, H. E.; Rheingold, A. L. Inorg. Chim. Acta 2015, 427, 168-172. Synthesis, structure, and luminescence of the "octahedral" cluster Cu₄I₄(rac-IsMePCH₂PMeIs)₂ (Is = 2,4,6-(i-Pr)₃C₆H₂).

64. Guino-o, M. A.; Zureick, A. H.; Blank, N. F.; Anderson, B. J.; Chapp, T. W.; Kim, Y.; Glueck, D. S.; Rheingold, A. L. Organometallics 2012, 31, 6900-6910. Synthesis and Structure of Platinum Bis(phospholane) Complexes Pt(diphos*)(R)(X), Catalyst Precursors for Asymmetric Phosphine Alkylation.

63. "Synthesis, Reactivity, and Resolution of a C₂-Symmetric, P-Stereogenic Benzodiphosphetane, a Building Block for Chiral Bis(phosphines)." Reynolds, S. C.; Hughes, R. P.; Glueck, D. S.; Rheingold, A. L. Org. Lett. 2012, 14, 4238-4241.

62. "Synthesis, Structure, Dynamics, and Selective Methylation of Platinum and Palladium Diphosphametallacyclobutane Complexes." Chapp, T. W.; Schoenfeld, A. J.; Sanderson, M. D.; Chang, C. L.; Glueck, D. S.; Golen, J. A.; Moore, C. E.; Rheingold, A. L. Organometallics 2012, 31, 5573-5585.

61. "Asymmetric Synthesis and Metal Complexes of a C₃-Symmetric P-Stereogenic Triphosphine, (R)-MeSi(CH₂PMe(t-Bu))₃ (MT-Siliphos)." Cain, M. F.; Glueck, D. S.; Golen, J. A.; Rheingold, A. L. Organometallics 2012, 31, 775-778.

60. "Selectivity via catalyst or substrate control in catalytic asymmetric transformations of bifunctional symmetrical substrates." Glueck, D. S. Catal. Sci. Technol. 2011, 1, 1099-1108.

59. "Synthesis and Structure of Gold and Platinum Menthyl Complexes." Zuzek, A. A.; Reynolds, S. C.; Glueck, D. S.; Golen, J. A.; Rheingold, A. L. Organometallics 2011, 30, 1812-1817.

58. "Electrochemistry of P(CH₂Fc)₃ and derivatives." Seibert, A. R.; Cain, M. F.; Glueck, D. S.; Nataro, C. J. Organomet. Chem. 2011, 696, 2259-2262.

57. "Synthesis, Structure and Spectroscopic Properties of 2,3-bis(diphenylphosphino)quinoxaline (dppQx) and Its Copper(I) Complexes." Cain, M. F.; Reynolds, S. C.; Anderson, B. J.; Glueck, D. S.; Golen, J. A.; Moore, C. E.; Rheingold, A. L. Inorg. Chim. Acta 2011, 369, 55-61.

56. "Synthesis and Structure of Intermediates in Copper-Catalyzed Alkylation of Diphenylphosphine." Cain, M. F.; Hughes, R. P.; Glueck, D. S.; Golen, J. A.; Moore, C. E.; Rheingold, A. L. Inorg. Chem. 2010, 49, 7650-7662.

55. "Effects of Linker Length on the Rate and Selectivity of Platinum-Catalyzed Asymmetric Alkylation of the Bis(isitylphosphino)alkanes IsHP(CH₂)_nPHIs (Is = 2,4,6-(i-Pr)₃C₆H₂, n = 1–5)." Chapp, T. W.; Schoenfeld, A. J.; Glueck, D. S. Organometallics 2010, 29, 2465-2473.

54. "Synthesis of Gold Phosphido Complexes Derived from Bis(secondary) Phosphines. Structure of Tetrameric [Au(MesP(CH₂)₃PMes)Au]₄." Lane, E. M.; Chapp, T. W.; Hughes, R. P.; Glueck, D. S.; Feland, B. C.; Bernard, G. M.; Wasylishen, R. E.; Rheingold, A. L. Inorg. Chem. 2010, 49, 3950-3957.

53. "Platinum-Catalyzed Asymmetric Alkylation of Bis(isitylphosphino)ethane: Stereoselectivity Reversal in Successive Formation of Two P-C Bonds." Chapp, T. W.; Glueck, D. S.; Golen, J. A.; Moore, C. E.; Rheingold, A. L. Organometallics 2010, 29, 378-388.

5. Glueck, D. S., Phosphiranes, Phosphirenes, and Heavier Analogues. In Comprehensive Heterocyclic Chemistry IV, Black, D. S.; Cossy, J.; Stevens, C. V., Eds. Elsevier: 2022; Vol. 1, pp 464-505.

4. Glueck, D. S. Modern Aspects of ³¹P NMR Spectroscopy. In Organophosphorus Chemistry: from Molecules to Applications; Iaroshenko, V., Ed.; Wiley-VCH: Weinheim, 2019, p 457-498.

3. Glueck, D. S. 1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene (S,S)-Me-DuPhos and 1,2-Bis((2R,5R)-2,5-dimethylphospholano)benzene (R,R)-Me-DuPhos, First Update. In e-EROS Encyclopedia of Reagents for Organic Synthesis; John Wiley and Sons: 2018.

2. Glueck, D. S. Top. Organomet. Chem. 2010, 31, 65-100. Recent Advances in Metal-Catalyzed C-P Bond Formation. (In C-X Bond Formation, Vigalok, A., Ed.)

1. "Hydrophosphination and Related Reactions," Denyce K. Wicht and David S. Glueck. In Catalytic Heterofunctionalization. From Hydroamination to Hydrozirconation; Togni, A., Grutzmacher, H., Eds.; Wiley-VCH: Weinheim, 2001, pp. 143-170.

1. "Method for Enantioselective Synthesis of Phosphorus-Stereogenic Phosphines." Scriban, C.; Glueck, D. S. (Trustees of Dartmouth College), US patent 8193392, 2012.
Link to USPTO page for this patent

4. "Phosphorus Compounds: Advanced Tools in Catalysis and Material Sciences." Glueck, D. S. J. Am. Chem. Soc. 2011, 133, 17520.

3. "Phosphorus Ligands in Asymmetric Catalysis: Synthesis and Applications, Volumes 1-3." Glueck, D. S. J. Am. Chem. Soc. 2008, 130, 14018.

2. "Macromolecules Containing Metal and Metal-Like Elements, Volume 7: Nanoscale Interactions of Metal-Containing Polymers." Glueck, D. S. J. Am. Chem. Soc. 2006, 128, 4919.

1. "Topics in Current Chemistry, 229: New Aspects in Phosphorus Chemistry III Edited by J.-P. Majoral," David S. Glueck. J. Am. Chem. Soc. 2004, 126, 4741.

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